How steelmaking may go carbon-free—by dropping its addiction to coal

By Maria Gallucci | February 5, 2021

steel mill furnaces at work Steel mill interior. Image courtesy of Payton Chung under Creative Commons License

Coal’s grip on the global electricity sector is loosening as more utilities and companies invest in renewable energy. But one major coal consumer—the steel industry—is finding it harder to kick its habit.

Steel companies make nearly 2 billion tons of high-strength material every year for bridges, buildings, railways, and roads. The furnaces that melt iron ore to make steel consume vast amounts of coal. As a result, the industry accounts for roughly 8 percent of annual carbon dioxide emissions, according to McKinsey and Company, as well as a toxic soup of air pollutants.

Steelmakers worldwide are facing mounting pressure from government regulators and consumers to decarbonize operations. Doing so is essential to limiting global warming to 1.5 degrees Celsius and staving off most of the worst effects of climate change, experts say. In recent months, the world’s three top producers—Europe’s ArcelorMittal, China’s Baowu Steel, and Japan’s Nippon Steel—committed to achieving net-zero emissions by 2050, echoing targets set in their home countries.

Outside Boston, in the industrial suburb of Woburn, one company is working to replace coal with electrons. Boston Metal, an outfit spun out of the Massachusetts Institute of Technology, uses electric currents to heat iron ore into a bright orange-white liquid, which converts into metal and cools as gray steel blocks. The process doesn’t create greenhouse gas emissions, and when powered with renewable electricity, can be completely emissions-free.

Tadeu Carneiro, the company’s CEO, said Boston Metal is “ushering in a new era of metallurgy.” The nine-year-old startup raised $50 million last month from a slew of investors, including the Bill Gates-led Breakthrough Energy Ventures and the venture capital arm of Australia’s BHP (formerly Broken Hill Proprietary), one of the world’s biggest mining companies. The new funding will allow it to build a demonstration plant in Woburn that can produce 25,000 tons of metal per year; so far, the company has made only several tons of steel in total.

Boston Metal’s approach is one of a handful of breakthrough technologies with the potential to decarbonize steelmaking. Companies are piloting systems across Europe that use hydrogen in furnaces in lieu of coal. In Brazil, some steel mills are mixing in biochar, which is made from agricultural waste. Other firms are continuing the use of coal, but are considering retrofitting facilities with carbon capture devices to negate emissions.

Testing and scaling technologies that remove the emissions from steelmaking isn’t the only challenge to decarbonizing the building material. Greener products must also compete in an industry with relatively low profit margins and an excess supply of inexpensive Chinese steel.

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To level the playing field, public agencies and private businesses will need to set policies that encourage buying emissions-free steel, or make it more expensive to purchase conventional supplies, said Nate Aden, a senior fellow at the World Resources Institute who studies industrial sector transformations. (California, for instance, limits the total amount of carbon emissions associated with steel and other materials used in state-backed construction projects.)

“We haven’t had nearly enough research and development in this space for the past couple decades,” Aden said. “It’s exciting.”

Coke and iron. About 70 percent of steel today is made how it’s always been made: in giant, extremely hot furnaces. Purified coal, or “coke,” is heated and melted with iron oxide and limestone, then injected with oxygen to reduce the carbon content of the mixture and to remove impurities.

Almost all other steel is made from scrap metal that’s melted down in an electric arc furnace. This approach doesn’t use coke as a raw material. But it does require significant amounts of electricity to heat metal to nearly 3,000 degrees Fahrenheit—and most of that power comes from coal-fired power plants

At Boston Metal’s research facility, the steelmaking process takes place inside a squat metal cylinder called an electrolytic cell. Electricity is fed in from the top and flows through a chimney-like tube made from a chromium-based alloy. The electric current then passes across a liquid solution made of iron oxide and other metallic minerals. This heats the oxide melt and drives chemical reactions that result in the production of oxygen gas and liquid iron. Oxygen bubbles to the top, while fortified iron pools at the chamber’s bottom and eventually hardens into steel.

Donald Sadoway, a professor of materials chemistry at MIT, said he first got the idea for “molten oxide electrolysis” decades ago while researching alternative ways to produce aluminum, another metal made via a carbon-intensive process. In 2012, he co-founded Boston Electrometallurgical (a.k.a. Boston Metal) with two partners, and they began testing the method in laboratory cells the size of highball tumbler glasses. The company now runs three pilot lines at the Woburn facility.

With the $50 million investment from Breakthrough, BHP, and others, Sadoway said the goal is to demonstrate the technology at a scale large enough to convince investors to back construction of an industrial facility. If that future plant comes to fruition, he estimates Boston Metal’s process will use about 20 percent less energy than a conventional blast furnace. And if the facility can use cheap, plentiful renewable electricity, perhaps from a hydropower plant, its steel would cost less than the competition.

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“At scale, we expect to make better metal at lower cost and with no carbon dioxide emissions,” he said.

Other approaches. While Boston Metal expands its efforts in electrolysis, many steel companies are placing their bets on hydrogen to curb emissions.

Hydrogen doesn’t emit greenhouse gases when burned and can be made by using renewable electricity to bust up water molecules (although most hydrogen today is made with natural gas, through a process called steam methane reforming). In steelmaking, hydrogen sets off a chemical reaction that removes oxygen from iron ore, eliminating the need for purified coal in the blast furnace.

Luxembourg-based ArcelorMittal is building a demonstration plant using this method—called hydrogen-DRI, for “direct reduced iron”—in Germany. Japan’s Mitsubishi Heavy Industries plans to trial the technology this year at a 250,000-ton per year steel plant in Austria. And in Sweden, steelmaker SSAB and its partners have built a pilot plant to produce hydrogen supplies and test hydrogen-DRI, using only hydroelectric power for both operations.

Building a hydrogen-based steel industry will require significant spending to not only build new plants but also produce, transport, and store green hydrogen. For these projects to be economically viable in the world of cheap steel, the prices of hydrogen and renewable electricity must drop considerably, while the price of carbon dioxide must rise, Aden wrote in a 2020 paper for Applied Energy as part of an international team of experts.

There’s another longer-term challenge for new, clean projects. Demand for steel is declining or stagnating in key markets, including the United States and Japan. Producers are already making more steel than the world needs. Meanwhile, construction companies and car makers are increasingly using lightweight aluminum, plastics, and even wood in their projects. That could make it harder to justify future investments or research, according to Aden.

Still, the steel industry remains an essential part of the world economy—as well as a significant source of the world’s emissions.

“What’s clear is that we’ll be needing steel for the next few decades,” Aden said. “So I think all these new projects are worthwhile.”

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Charles Forsberg
Charles Forsberg
2 years ago

The problem is not decarbonizing steel production, the problem is cost. Depending upon who you believe, decarbonized steel will be 20 to 100% more expensive than from coal without carbon capture and sequestration. Steel making with coal and CCS may turn out to be the cheap technology.. Electricity for electrolytic routes or hydrogen production is about 6 times more expensive than coal. That type of price increase implies reductions in the global standard of living and major increases in the cost of wind where the steel towers are major cost factor. The steel input into a wind system is about… Read more »

joseph smith
joseph smith
2 years ago

Traditional blast furnaces use coke (coal with the volatiles cooked out) and limestone. This plus the minerals in the iron ore produce a slag. The slag carries away impurities that hydrogen reduction leaves behind. Also , hydrogen makes steel very brittle? Ever wonder why Chinese and Indian steel is mostly crap? Direct reduction with hydrogen. Also, making hydrogen requires immense amounts of energy. That energy has to come from somewhere. And hydrogen leaks out of anything very easily and is terrifically explosive-FAR more dangerous than natural gas. I could not have my hydrogen tank in the lab- had to leave… Read more »